Plaster has been used as an interior and exterior wall finish for at least 9,000 years, with the earliest known examples found at Catalhoyuk in modern Turkey, dating to approximately 7000 BCE. At its most fundamental level, plaster is a mixture of a binder, an aggregate, and water, applied in a plastic state that hardens through either a drying process or a chemical setting reaction. The choice between plaster types determines not only the finished appearance but also the breathability, durability, and workability of the wall surface.
Lime Plaster: The Traditional Choice
Lime plaster is made from calcium hydroxide, known as slaked lime or builder's lime, mixed with sand and water. The lime is produced by heating limestone (calcium carbonate, CaCO3) to approximately 900 degrees Celsius in a kiln, driving off carbon dioxide to produce quicklime (calcium oxide, CaO). Water is then added in a process called slaking, which generates significant heat and converts the quicklime to calcium hydroxide. The carbonation reaction then proceeds over weeks and months as the plaster absorbs carbon dioxide from the air and converts back to calcium carbonate, recreating a limestone-like surface.
Lime plaster has a set working time of several hours and hardens slowly enough that a single coat can be worked and reworked. Its high vapour permeability, typically measured at 20 to 30 perms for a 20 mm thickness, allows walls to breathe, managing moisture in solid-wall historic buildings. This breathability prevents trapped moisture and associated decay in older masonry structures. The compressive strength of lime plaster ranges from 1 to 4 MPa after carbonation, significantly lower than modern alternatives but more than adequate for interior finishes.
Gypsum Plaster: The Modern Standard
Gypsum plaster, known as plaster of Paris when in its hemihydrate form (CaSO4·1/2H2O), hardens through a chemical setting reaction rather than simple drying. When mixed with water, the hemihydrate rehydrates into calcium sulfate dihydrate (CaSO4·2H2O) in an exothermic reaction that takes 20 to 90 minutes depending on additives. The interlocking needle-like crystal structure that forms during setting gives gypsum plaster its smooth, hard finish and compressive strength of 6 to 12 MPa.
Modern gypsum plasters include retarding agents that extend working time and lightweight aggregates such as perlite or vermiculite that improve coverage and thermal performance. Gypsum plaster cannot be used externally or in continuously damp conditions because the gypsum slowly dissolves and loses structural integrity. The setting reaction means gypsum plaster reaches full strength within hours, not weeks, making it far faster for construction schedules than traditional lime.